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Nov 7, 2023Ā·Advanced Functional Materials
24 cites
Ionic Conductivity Switchable and Shape Changeable Smart Skins with Azobenzene‐Based Ionic Reactive Mesogens

Mintaek Oh, Seok‐In Lim, Junhwa Jang, Youngjae Wi Ā· 10 authors

Abstract To develop smart ionic skins capable of multi‐responsiveness and switchable ionic conductivity, a stimuli‐responsive and ionic conductive azobenzene‐based monomer is newly synthesized, uniaxially oriented, and polymerized for anisotropic liquid crystal elastomers (LCEs). Since the uniaxially oriented monodomain LCE with ionic asymmetric azobenzene monomers (i‐AAM) is prepared by thermal oligomerization, uniaxial stretching, and subsequent photopolymerization, the stimuli‐responsive i‐AAM LCE is thermally contracted by increasing the temperature above T NI as well as is bent along the aligned direction by irradiating it with UV light. In addition to the change of shape, the ionic conductivity of the LCE is reversible in response to heat and light stimuli. Polydomain i‐AAM LCE polymerized without the stretching process exhibits higher ionic conductivity than stretched monodomain LCE due to the initially formed stable ionic pathways. Ionic conductivity can also be switched simultaneously by polarity changes in response to the photoisomerization of i‐AAM, increased mobility from heat, and an elastic mechanoresponse from external stresses. These i‐AAM LCE‐based soft grippers exhibit stimuli‐responsive grasping and releasing actuation and detect ionic conductivity switches finely, suggesting potential as smart skins for advanced soft robots.

Open access
Advanced Materials and Mechanics
Advanced Sensor and Energy Harvesting Materials
Polymer composites and self-healing
Original source
Jun 10, 2011Ā·IEEE/ASME Transactions on Mechatronics
36 cites
Smart Radially Folding Structures

Andrew T. Conn, Jonathan Rossiter

In this paper, we present novel methods for exploiting passive and active radially folding mechanisms for reactive and dynamic structures. These enable the application of radially folding structures in domains including fluidics, medical stents, and auxetic materials. A compact form of elastic deployment utilizing linkage strain energy is proposed using beam theory analysis. Elastic strain energy is also shown to produce bistable folding behavior, with two low energy states at full contraction and full expansion, and a bistable switching point at some intermediate position. Polymeric smart materials are investigated for driving active folding. These materials can be readily exploited through the features of the folding structure including its ability to resolve 1-D, 2-D, and 3-D actuation strains into a more effective single degree-of-freedom linear, areal, volumetric or rotational output. The elastic and solid-state nature of many polymeric smart materials means they can implement elastic deployment and bistability. A thermally-activated shape memory polymer is shown to fold a 4-segment structure from expanded to contracted states. Experimental testing of an 8-segment dielectric elastomer actuator prototype demonstrates that radially folding structures can resolve large biaxial planar strains generated by dielectric elastomers into a single linear or rotational output stroke.

Dielectric materials and actuators
Polymer composites and self-healing
Advanced Materials and Mechanics
Original source