Nadia Dahmani, Imen Ben Salem, Syed Muhammad Salman Bukhari
Abstract Air quality (AQ) related health risks are increasing globally, creating urgent demand for artificial intelligence (AI) systems that are privacy-preserving, transparent, and auditable. Although Federated Learning (FL), Distributed Ledger Technologies (DLT), and Explainable AI (XAI) are widely recognized as core components of trustworthy AI, existing research remains divided across technical and application domains. This study conducts a computational, multistage systematic review (SR) of scholarly literature records published between 2011 and 2025 using the Semantic Scholar Graph API with intersection and union search strategies. A total of 13,458 records were retrieved and refined into a research-grade corpus of 7,215 publications through DOI-based deduplication, abstract quality diagnostics, venue and publication type screening, and exclusion of non-research artifacts. We used synergy detection, bibliometric analysis, and semantic clustering to study how these technologies are combined and distributed across research domains. The semantic clustering was performed using Sentence-BERT embeddings and UMAP. The results reveal a major structural gap. Among the 6,942 technology-tagged publications in the final 7,215-paper corpus, only 25 studies were identified as triple-synergy candidates that jointly mention or report the combined use of FL, DLT, and XAI, accounting for approximately 0.4%. Among these 25 triple-synergy publications, only two studies (8%) addressed climate or environmental applications, whereas 23 studies (92%) focused on healthcare or general AI. Semantic analysis further categorizes the studies into four areas: environmental sensing, provenance, governance, and clinical risk modeling. This division creates a critical challenge for scalable deployment, cross-domain interoperability, and policy-ready AI systems for AQ-health decision-making. To address this gap, we propose the Green-AI-Trust Stack, a layered architectural framework that integrates three complementary pillars (FL for privacy-preserving distributed learning, DLT for verifiable data and model provenance, and XAI for interpretable inference and decision support within a unified AQI-health pipeline). The findings provide practical direction for researchers, policymakers, and practitioners by identifying key research gaps, methodological needs, and future opportunities for reliable, auditable, and explainable AQI-health AI systems.